How does a carpool/vanpool relate to a shared car service/company when it comes to the preferred parking requirements of this credit?

If a proper contract agreement of two years and designated space are provided through an alternative compliance method, then a shared car service may be accepted as a “carpool or vanpool” substitute. See LEED Interpretation ID#3138, 1/26/2005, in which Reviewers define car share services, and LEED Interpretation ID#3137, 5/24/2004, in which Zipcar is discussed as a carpool substitute for residential projects.

How does one account for off-site parking. Should the LEED boundary encompass this parking? Or alternatively may the project pursue the "no new parking" option?

The Minimum Program Requirements supplemental guidance document covers these situations in some detail. The boundary needs to include "contiguous land that is associated with and supports normal building operations."