The LEED Reference Guide states that entryway systems need to be on the interior of the building or in an interior vestibule. It is recommended that projects pursuing this credit with the intent of using an exterior entryway system (either permanent or rollout) consult the GBCI or your certification board via email to verify credit compliance. It is usually accepted that exterior walk-off systems are allowed if they are properly sheltered from weather; that would typically mean some kind of roof, but additional shelter may be warranted depending on local conditions.