Can crushed concrete, masonry or asphalt being reused onsite qualify as materials reuse?

No. According to the LEED glossary, these materials are considered remanufactured, and therefore do not qualify as reuse. Under the Related Credits section in the LEED Reference Guide, it states that “Remanufactured materials are not considered a reuse of the material and do not contribute toward this credit. However, these materials can contribute toward MR Credit 2: Construction Waste Management, or MR Credit 4: Recycled Content."

We are demolishing an existing building, crushing the concrete and stone, and using it as fill onsite. Does this count under MRc3?

No, as the material is being "re-manufactured' into something else, it is different than reuse, where products and materials are used intact, but in different applications or locations. The primary environmental attributes for this case are construction waste management (MRc2), and potentially recycled content (MRc4), and regionality (MRc5). The intent of this credit is to extend the life of existing building materials.